There are 2 main definitions of national road in English:

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national road1

Line breaks: na|tion¦al road

Entry from British & World English dictionary

noun

(In South Africa) any of a network of major intercity roads: the old national road tells you you are going somewhere important

Definition of national road in:

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There are 2 main definitions of national road in English:

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National Road2

Syllabification: Na·tion·al Road
A historic highway that in the early 19th century led from Maryland through the Appalachian Mountains to St. Louis in Missouri. It was once the major route for western expansion.

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